n1 ~ 2 n4 CHF3 .

.. , .., .., W. HERREBOUT *

* Department of Chemistry,RUCA,Groenborgerlaan 171, B2020 Antwerp, Belgium

n1 ~ 2 n4(A1) CHF3 F3CH...B, B = O(CD3)2 , N(CD3)3, NH3 NC5D5. , n4. n1() . F3CH...N(CD3)3 D n10= - 40 -1 D n1 = - 23 -1. F3CH...NH33 F3CH...NC5D5 : D n10 <0 D n1 >0 ( "-" ).
: ( n1)/(2 n4) ~30, 1.1 - 2.5. " " 2 n4 , Q1. - , W √ R0=<00|m |020>/<00|m |10> ( ), - (W<0, √R0>0 ). - , - . - .
, , ( ), ( a ikj, xik ) , .



:
1. CF4 - .

2. - NF3 + AR

3.- : .

4.CRYOSPECTRA OF HYDROGEN DEUTERIDE DISSOLVED IN LIQUID NEON: NEW EFFECTS AND THEIR INTERPRETATION.

5. - (SF6)2 (SiF4)2. (1-3) Ar (11)

7.DENSITY EVOLUTION OF THE ps TIME-DOMAIN CARS RESPONSES FROM THE CO2 GAS.

8. .

9. SF6 CF4 .

10. - .